2D halide perovskite semiconductors have shown a variety of applications in recent years, mainly in photovoltaics, attracting a plethora of scientists to this developing multidisciplinary field. The primary goal for this Thesis, is to further exploring the field, by synthesizing new 2D hybrid halide perovskites and trying to optimize certain aspects of the crystal and electronic band structure. Towards this end, the new organic diammonium spacer (2-halo, 1,3-diammino propane, DicX, X = Br, I) was introduced, in an attempt to examine the effect of the organic halide in the photophysical properties of the layered perovskites. The new spacer was employed towards the synthesis of the 2D homologous series (DicI)(CH₃NH₃)_n-1PbnI_3n+1(n = 1-3) as well as the synthesis of members of the corresponding 2D lead-free compounds based on ordered double perovskites combining Ag⁺ and Bi³⁺ double perovskites.

As it was shown from optical measurements in the visible range, new compounds exhibit stable excitons at room temperature emitting in the wavelength range λ = 500-650 nm consistent with their Multiple Quantum Well electronic structure. However, unlike other derivatives of the 2D perovskites, the binding energy of the materials appears to be significantly reduced, as a result of the organic spacer. The extra organ iodide in the spacer reduces the dielectric contrast between the organic and the inorganic components whereas the interlayer distance between the perovskite sheets is significantly reduced from the short carbon chain. As band structure calculations also support, the new materials effectively behave as bulk perovskites, resulting in a charge-transport in all three dimensions, a property that may have great impact in the application of these materials in solar cells. In an attempt to take advantage of this property, thin films of these layered 2D halide perovskites were fabricated and characterized. Future work on these materials will deal with the manufacture and characterization of full solar cells devices, where it is anticipated that we will be able to obtain a significant increase in the photo-generated current which may lead to an overall improved power-conversion efficiency.

Among the numerous applications protein-polymer conjugates are expected to find in material sciences, their potential to enhance the activity of enzymes or differentiate it on demand is of particular interest. Primary goal of this Thesis was to explore the synthesis of protein-polymer conjugates by grafting polymers from the unspecific AaeUPO peroxygenase, a protein isolated from the fungus Agrocybe aegerita. A variety of monomers were used to synthesize hydrophilic, hydrophobic and responsive bioconjugates via controlled radical polymerization approaches. AaeUPO bioconjugates were characterized with spectroscopy (NMR, IR) and chromatography (GPC, electrophoresis). Preliminary studies (NMR spectroscopy) allowed to correlate the activity of the biohybrid with that of the native AaeUPO peroxygenase.